PRZEDMIOTEM OFERTY JEST KOD DOSTĘPOWY DO KSIĄŻKI ELEKTRONICZNEJ (EBOOK)

KSIĄŻKA JEST DOSTĘPNA NA ZEWNĘTRZNEJ PLATFORMIE. KSIĄŻKA NIE JEST W POSTACI PLIKU.

Reaction Mechanism Focused with a Structure and Function Framework Organic Chemistry: Structure and Function, 8e maintains the classic framework with a logical organization that an organic molecule’s structure will determine its function and strengthens a focus on helping students understand reactions, mechanisms, and synthetic analysis and their practical applications. The eighth edition presents a refined methodology, rooted in teaching expertise to promote student understanding and build problem-solving skills. Organic Chemistry is now supported in Achieve, Macmillan’s new online learning platform. Achieve is the culmination of years of development work put toward creating the most powerful online learning tool for chemistry students. Achieve includes an interactive e-Book as well as our renowned assessments, and new tutorial questions. Students will be able to focus their study with adaptive quizzing and more easily visualise organic chemistry with new model kit questions and our intuitive MolDraw drawing tool.

• Autorzy: Peter Vollhardt Neil Schore
• Wydawnictwo: Macmillan Learning
• Data wydania: 2018
• Wydanie: 8
• Liczba stron:
• Forma publikacji: ePub (online)
• Język publikacji: angielski
• ISBN: 9781319189044

BRAK MOŻLIWOŚCI POBRANIA PLIKU. Drukowanie: OGRANICZENIE DO 2 stron. Kopiowanie: OGRANICZENIE DO 2 stron.

• Front Matter
• Cover Page
• Inside Front Cover
• About the Authors
• Title Page
• Copyright Page
• Brief Contents
• Contents
• Preface: A User’s Guide to Organic Chemistry: Structure and Function
• Chapter 1 Structure and Bonding in Organic Molecules
• 1-1 The Scope of Organic Chemistry: An Overview
• Real Life: Nature 1-1 Urea: From Urine to Wöhler’s Synthesis to Industrial Fertilizer
• 1-2 Coulomb Forces: A Simplified View of Bonding
• 1-3 Ionic and Covalent Bonds: The Octet Rule
• 1-4 Electron-Dot Model of Bonding: Lewis Structures
• 1-5 Resonance Forms
• 1-6 Atomic Orbitals: A Quantum Mechanical Description of Electrons Around the Nucleus
• 1-7 Molecular Orbitals and Covalent Bonding
• 1-8 Hybrid Orbitals: Bonding in Complex Molecules
• 1-9 Structures and Formulas of Organic Molecules
• 1-10 A General Strategy for Solving Problems in Organic Chemistry
• Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 2 Structure and Reactivity
• Acids and Bases, Polar and Nonpolar Molecules
• 2-1 Kinetics and Thermodynamics of Simple Chemical Processes
• 2-2 Keys to Success: Using Curved “Electron-Pushing” Arrows to Describe Chemical Reactions
• 2-3 Acids and Bases
• Real Life: Medicine 2-1 Stomach Acid, Peptic Ulcers, Pharmacology, and Organic Chemistry
• 2-4 Functional Groups: Centers of Reactivity
• 2-5 Straight-Chain and Branched Alkanes
• 2-6 Naming the Alkanes
• 2-7 Structural and Physical Properties of Alkanes
• Real Life: Nature 2-2 “Sexual Swindle” by Means of Chemical Mimicry
• 2-8 Rotation about Single Bonds: Conformations
• 2-9 Rotation in Substituted Ethanes
• 2-10 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 3 Reactions of Alkanes
• Bond-Dissociation Energies, Radical Halogenation, and Relative Reactivity
• 3-1 Strength of Alkane Bonds: Radicals
• 3-2 Structure of Alkyl Radicals: Hyperconjugation
• 3-3 Conversion of Petroleum: Pyrolysis
• Real Life: Sustainability 3-1 Sustainability and the Needs of the 21st Century: “Green” Chemistry
• 3-4 Chlorination of Methane: The Radical Chain Mechanism
• 3-5 Other Radical Halogenations of Methane
• 3-6 Keys to Success: Using the “Known” Mechanism as a Model for the “Unknown”
• 3-7 Chlorination of Higher Alkanes: Relative Reactivity and Selectivity
• 3-8 Selectivity in Radical Halogenation with Fluorine and Bromine
• 3-9 Synthetic Radical Halogenation
• Real Life: Medicine 3-2 Chlorination, Chloral, and DDT: The Quest to Eradicate Malaria
• 3-10 Synthetic Chlorine Compounds and the Stratospheric Ozone Layer
• 3-11 Combustion and the Relative Stabilities of Alkanes
• 3-12 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 4 Cycloalkanes
• 4-1 Names and Physical Properties of Cycloalkanes
• 4-2 Ring Strain and the Structure of Cycloalkanes
• 4-3 Cyclohexane: A Strain-Free Cycloalkane
• 4-4 Substituted Cyclohexanes
• 4-5 Larger Cycloalkanes
• 4-6 Polycyclic Alkanes
• 4-7 Carbocyclic Products in Nature
• Real Life: Materials 4-1 Cyclohexane, Adamantane, and Diamandoids: Diamond “Molecules”
• Real Life: Medicine 4-2 Cholesterol: How Is It Bad and How Bad Is It?
• Real Life: Medicine 4-3 Controlling Fertility: From “the Pill” to RU-486 to Male Contraceptives
• 4-8 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 5 Stereoisomers
• 5-1 Chiral Molecules
• Real Life: Nature 5-1 Chiral Substances in Nature
• 5-2 Optical Activity
• 5-3 Absolute Configuration: R,S Sequence Rules
• 5-4 Fischer Projections
• 5-5 Molecules Incorporating Several Stereocenters: Diastereomers
• Real Life: Nature 5-2 Stereoisomers of Tartaric Acid
• 5-6 Meso Compounds
• 5-7 Stereochemistry in Chemical Reactions
• Real Life: Medicine 5-3 Chiral DrugsRacemic or Enantiomerically Pure?
• Real Life: Medicine 5-4 Why Is Nature “Handed”?
• 5-8 Resolution: Separation of Enantiomers
• 5-9 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 6 Properties and Reactions of Haloalkanes
• Bimolecular Nucleophilic Substitution
• 6-1 Physical Properties of Haloalkanes
• Real Life: Medicine 6-1 Fluorinated Pharmaceuticals
• 6-2 Nucleophilic Substitution
• 6-3 Reaction Mechanisms Involving Polar Functional Groups: Using “Electron-Pushing” Arrows
• 6-4 A Closer Look at the Nucleophilic Substitution Mechanism: Kinetics
• 6-5 Frontside or Backside Attack? Stereochemistry of the SN2 Reaction
• 6-6 Consequences of Inversion in SN2 Reactions
• 6-7 Structure and SN2 Reactivity: The Leaving Group
• 6-8 Structure and SN2 Reactivity: The Nucleophile
• 6-9 Keys to Success: Choosing Among Multiple Mechanistic Pathways
• 6-10 Structure and SN2 Reactivity: The Substrate
• 6-11 The SN2 Reaction at a Glance
• 6-12 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 7 Further Reactions of Haloalkanes
• Unimolecular Substitution and Pathways of Elimination
• 7-1 Solvolysis of Tertiary and Secondary Haloalkanes
• 7-2 Unimolecular Nucleophilic Substitution
• 7-3 Stereochemical Consequences of SN1 Reactions
• 7-4 Effects of Solvent, Leaving Group, and Nucleophile on Unimolecular Substitution
• 7-5 Effect of the Alkyl Group on the SN1 Reaction: Carbocation Stability
• Real Life: Medicine 7-1 Unusually Stereoselective SN1 Displacement in Anticancer Drug Synthesis
• 7-6 Unimolecular Elimination: E1
• 7-7 Bimolecular Elimination: E2
• 7-8 Keys to Success: Substitution versus EliminationStructure Determines Function
• 7-9 Summary of Reactivity of Haloalkanes
• 7-10 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 8 Hydroxy Functional Group: Alcohols
• Properties, Preparation, and Strategy of Synthesis
• 8-1 Naming the Alcohols
• 8-2 Structural and Physical Properties of Alcohols
• 8-3 Alcohols as Acids and Bases
• 8-4 Synthesis of Alcohols by Nucleophilic Substitution
• 8-5 Synthesis of Alcohols: Oxidation–Reduction Relation Between Alcohols and Carbonyl Compounds
• Real Life: Medicine 8-1 Oxidation and Reduction in the Body
• Real Life: Medicine 8-2 Don’t Drink and Drive: The Breath Analyzer Test
• 8-6 Organometallic Reagents: Sources of Nucleophilic Carbon for Alcohol Synthesis
• 8-7 Organometallic Reagents in the Synthesis of Alcohols
• 8-8 Keys to Success: An Introduction to Synthetic Strategy
• Real Life: Chemistry 8-3 What Magnesium Does Not Do, Copper Can: Alkylation of Organometallics
• 8-9 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 9 Further Reactions of Alcohols and the Chemistry of Ethers
• 9-1 Reactions of Alcohols with Base: Preparation of Alkoxides
• 9-2 Reactions of Alcohols with Strong Acids: Alkyloxonium Ions in Substitution and Elimination Reactions of Alcohols
• 9-3 Carbocation Rearrangements
• 9-4 Esters from Alcohols and Haloalkane Synthesis
• 9-5 Names and Physical Properties of Ethers
• 9-6 Williamson Ether Synthesis
• Real Life: Nature 9-1 Chemiluminescence of 1,2-Dioxacyclobutanes
• 9-7 Synthesis of Ethers: Alcohols and Mineral Acids
• 9-8 Reactions of Ethers
• Real Life: Medicine 9-2 Protecting Groups in the Synthesis of Testosterone
• 9-9 Reactions of Oxacyclopropanes
• Real Life: Chemistry 9-3 Hydrolytic Kinetic Resolution of Oxacyclopropanes
• 9-10 Sulfur Analogs of Alcohols and Ethers
• 9-11 Physiological Properties and Uses of Alcohols and Ethers
• 9-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 10 Using Nuclear Magnetic Resonance Spectroscopy to Deduce Structure
• 10-1 Physical and Chemical Tests
• 10-2 Defining Spectroscopy
• 10-3 Hydrogen Nuclear Magnetic Resonance
• Real Life: Spectroscopy 10-1 Recording an NMR Spectrum
• 10-4 Using NMR Spectra to Analyze Molecular Structure: The Proton Chemical Shift
• 10-5 Tests for Chemical Equivalence
• Real Life: Medicine 10-2 Magnetic Resonance Imaging (MRI) in Medicine
• 10-6 Integration of NMR Signals
• 10-7 Spin–Spin Splitting: The Effect of Nonequivalent Neighboring Hydrogens
• 10-8 Spin–Spin Splitting: Some Complications
• Real Life: Spectroscopy 10-3 The Nonequivalence of Diastereotopic Hydrogens
• 10-9 Carbon-13 Nuclear Magnetic Resonance
• Real Life: Spectroscopy 10-4 How to Determine Atom Connectivity in NMR
• Real Life: Medicine 10-5 Structural Characterization of Natural and “Unnatural” Products: An Antioxidant from Grape Seeds and a Fake Drug in Herbal Medicines
• 10-10 Worked Examples: Integrating the Concepts
• Important Concepts
• Problems
• Chapter 11 Alkenes: Infrared Spectroscopy and Mass Spectrometry
• 11-1 Naming the Alkenes
• 11-2 Structure and Bonding in Ethene: The Pi Bond
• 11-3 Physical Properties of Alkenes
• 11-4 Nuclear Magnetic Resonance of Alkenes
• Real Life: Medicine 11-1 NMR of Complex Molecules: The Powerfully Regulating Prostaglandins
• 11-5 Catalytic Hydrogenation of Alkenes: Relative Stability of Double Bonds
• 11-6 Preparation of Alkenes from Haloalkanes and Alkyl Sulfonates: Bimolecular Elimination Revisited
• 11-7 Preparation of Alkenes by Dehydration of Alcohols
• 11-8 Infrared Spectroscopy
• 11-9 Measuring the Molecular Mass of Organic Compounds: Mass Spectrometry
• Real Life: Medicine 11-2 Detecting Performance-Enhancing Drugs Using Mass Spectrometry
• 11-10 Fragmentation Patterns of Organic Molecules
• 11-11 Degree of Unsaturation: Another Aid to Identifying Molecular Structure
• 11-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 12 Reactions of Alkenes
• 12-1 Why Addition Reactions Proceed: Thermodynamic Feasibility
• 12-2 Catalytic Hydrogenation
• 12-3 Basic and Nucleophilic Character of the Pi Bond: Electrophilic Addition of Hydrogen Halides
• 12-4 Alcohol Synthesis by Electrophilic Hydration: Thermodynamic Control
• 12-5 Electrophilic Addition of Halogens to Alkenes
• 12-6 The Generality of Electrophilic Addition
• 12-7 Oxymercuration–Demercuration: A Special Electrophilic Addition
• Real Life: Medicine 12-1 Juvenile Hormone Analogs in the Battle Against Insect-Borne Diseases
• 12-8 Hydroboration–Oxidation: A Stereospecific Anti-Markovnikov Hydration
• 12-9 Diazomethane, Carbenes, and Cyclopropane Synthesis
• 12-10 Oxacyclopropane (Epoxide) Synthesis: Epoxidation by Peroxycarboxylic Acids
• 12-11 Vicinal Syn Dihydroxylation with Osmium Tetroxide
• Real Life: Medicine 12-2 Synthesis of Antitumor Drugs: Sharpless Enantioselective Oxacyclopropanation (Epoxidation) and Dihydroxylation
• 12-12 Oxidative Cleavage: Ozonolysis
• 12-13 Radical Additions: Anti-Markovnikov Product Formation
• 12-14 Dimerization, Oligomerization, and Polymerization of Alkenes
• 12-15 Synthesis of Polymers
• 12-16 Ethene: An Important Industrial Feedstock
• 12-17 Alkenes in Nature: Insect Pheromones
• Real Life: Medicine 12-3 Alkene Metathesis Transposes the Termini of Two Alkenes: Construction of Rings
• 12-18 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 13 Alkynes
• The Carbon–Carbon Triple Bond
• 13-1 Naming the Alkynes
• 13-2 Properties and Bonding in the Alkynes
• 13-3 Spectroscopy of the Alkynes
• 13-4 Preparation of Alkynes by Double Elimination
• 13-5 Preparation of Alkynes from Alkynyl Anions
• 13-6 Reduction of Alkynes: The Relative Reactivity of the Two Pi Bonds
• 13-7 Electrophilic Addition Reactions of Alkynes
• 13-8 Anti-Markovnikov Additions to Triple Bonds
• 13-9 Chemistry of Alkenyl Halides
• Real Life: Synthesis 13-1 Metal-Catalyzed Stille, Suzuki, and Sonogashira Coupling Reactions
• 13-10 Ethyne as an Industrial Starting Material
• 13-11 Alkynes in Nature and in Medicine
• 13-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 14 Delocalized Pi Systems
• Investigation by Ultraviolet and Visible Spectroscopy
• 14-1 Overlap of Three Adjacent p Orbitals: Electron Delocalization in the 2-Propenyl (Allyl) System
• 14-2 Radical Allylic Halogenation
• 14-3 Nucleophilic Substitution of Allylic Halides: SN1 and SN2
• 14-4 Allylic Organometallic Reagents: Useful Three-Carbon Nucleophiles
• 14-5 Two Neighboring Double Bonds: Conjugated Dienes
• 14-6 Electrophilic Attack on Conjugated Dienes: Kinetic and Thermodynamic Control
• 14-7 Delocalization Among More than Two Pi Bonds: Extended Conjugation and Benzene
• 14-8 A Special Transformation of Conjugated Dienes: Diels-Alder Cycloaddition
• Real Life: Materials 14-1 Organic Polyenes Conduct Electricity
• Real Life: Sustainability 14-2 The Diels-Alder Reaction is “Green”
• 14-9 Electrocyclic Reactions
• 14-10 Polymerization of Conjugated Dienes: Rubber
• 14-11 Electronic Spectra: Ultraviolet and Visible Spectroscopy
• Real Life: Spectroscopy 14-3 The Contributions of IR, MS, and UV to the Characterization of Viniferone
• 14-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Interlude
• A Summary of Organic Reaction Mechanisms
• Chapter 15 Benzene and Aromaticity
• Electrophilic Aromatic Substitution
• 15-1 Naming the Benzenes
• 15-2 Structure and Resonance Energy of Benzene: A First Look at Aromaticity
• 15-3 Pi Molecular Orbitals of Benzene
• 15-4 Spectral Characteristics of the Benzene Ring
• Real Life: Materials 15-1 Compounds Made of Pure Carbon: Graphite, Graphene, Diamond, and Fullerenes
• 15-5 Polycyclic Aromatic Hydrocarbons
• 15-6 Other Cyclic Polyenes: Hückel’s Rule
• 15-7 Hückel’s Rule and Charged Molecules
• 15-8 Synthesis of Benzene Derivatives: Electrophilic Aromatic Substitution
• 15-9 Halogenation of Benzene: The Need for a Catalyst
• 15-10 Nitration and Sulfonation of Benzene
• 15-11 Friedel-Crafts Alkylation
• 15-12 Limitations of Friedel-Crafts Alkylations
• 15-13 Friedel-Crafts Acylation
• 15-14 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 16 Electrophilic Attack on Derivatives of Benzene
• Substituents Control Regioselectivity
• 16-1 Activation or Deactivation by Substituents on a Benzene Ring
• 16-2 Directing Electron-Donating Effects of Alkyl Groups
• 16-3 Directing Effects of Substituents in Conjugation with the Benzene Ring
• Real Life: Materials 16-1 Explosive Nitroarenes: TNT and Picric Acid
• 16-4 Electrophilic Attack on Disubstituted Benzenes
• 16-5 Keys to Success: Synthetic Strategies Toward Substituted Benzenes
• 16-6 Reactivity of Polycyclic Benzenoid Hydrocarbons
• 16-7 Polycyclic Aromatic Hydrocarbons and Cancer
• 16-8 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 17 Aldehydes and Ketones
• The Carbonyl Group
• 17-1 Naming the Aldehydes and Ketones
• 17-2 Structure of the Carbonyl Group
• 17-3 Spectroscopic Properties of Aldehydes and Ketones
• 17-4 Preparation of Aldehydes and Ketones
• 17-5 Reactivity of the Carbonyl Group: Mechanisms of Addition
• 17-6 Addition of Water to Form Hydrates
• 17-7 Addition of Alcohols to Form Hemiacetals and Acetals
• 17-8 Acetals as Protecting Groups
• 17-9 Nucleophilic Addition of Ammonia and Its Derivatives
• Real Life: Biochemistry 17-1 Imines Mediate the Biochemistry of Amino Acids
• 17-10 Deoxygenation of the Carbonyl Group
• 17-11 Addition of Hydrogen Cyanide to Give Cyanohydrins
• 17-12 Addition of Phosphorus Ylides: The Wittig Reaction
• 17-13 Oxidation by Peroxycarboxylic Acids: The Baeyer-Villiger Oxidation
• 17-14 Oxidative Chemical Tests for Aldehydes
• 17-15 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 18 Enols, Enolates, and the Aldol Condensation
• ?,ß-Unsaturated Aldehydes and Ketones
• 18-1 Acidity of Aldehydes and Ketones: Enolate Ions
• 18-2 Keto–Enol Equilibria
• 18-3 Halogenation of Aldehydes and Ketones
• 18-4 Alkylation of Aldehydes and Ketones
• 18-5 Attack by Enolates on the Carbonyl Function: Aldol Condensation
• Real Life: Biology And Medicine 18-1 Stereoselective Aldol Reactions in Nature and in the Laboratory: “Organocatalysis”
• 18-6 Crossed Aldol Condensation
• 18-7 Keys to Success: Competitive Reaction Pathways and the Intramolecular Aldol Condensation
• Real Life: Nature 18-2 Absorption of Photons by Unsaturated Aldehydes Enables Vision
• 18-8 Properties of [H9251],[H9252]-Unsaturated Aldehydes and Ketones
• 18-9 Conjugate Additions to [H9251],[H9252]-Unsaturated Aldehydes and Ketones
• 18-10 1,2- and 1,4-Additions of Organometallic Reagents
• 18-11 Conjugate Additions of Enolate Ions: Michael Addition and Robinson Annulation
• 18-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 19 Carboxylic Acids
• 19-1 Naming the Carboxylic Acids
• 19-2 Structural and Physical Properties of Carboxylic Acids
• 19-3 Spectroscopy and Mass Spectrometry of Carboxylic Acids
• 19-4 Acidic and Basic Character of Carboxylic Acids
• 19-5 Carboxylic Acid Synthesis in Industry
• 19-6 Methods for Introducing the Carboxy Functional Group
• 19-7 Substitution at the Carboxy Carbon: The Addition–Elimination Mechanism
• 19-8 Carboxylic Acid Derivatives: Acyl Halides and Anhydrides
• 19-9 Carboxylic Acid Derivatives: Esters
• 19-10 Carboxylic Acid Derivatives: Amides
• 19-11 Reduction of Carboxylic Acids by Lithium Aluminum Hydride
• 19-12 Bromination Next to the Carboxy Group: The Hell-Volhard-Zelinsky Reaction
• 19-13 Biological Activity of Carboxylic Acids
• Real Life: Materials 19-1 Long-Chain Carboxylates and Sulfonates Make Soaps and Detergents
• Real Life: Health 19-2 Artery-Clogging Trans Fatty Acids Phasing Out
• Real Life: Materials 19-3 Green Plastics, Fibers, and Energy from Biomass-Derived Hydroxyesters
• 19-14 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 20 Carboxylic Acid Derivatives
• 20-1 Relative Reactivities, Structures, and Spectra of Carboxylic Acid Derivatives
• 20-2 Chemistry of Acyl Halides
• 20-3 Chemistry of Carboxylic Anhydrides
• 20-4 Chemistry of Esters
• 20-5 Esters in Nature: Waxes, Fats, Oils, and Lipids
• Real Life: Sustainability 20-1 Moving Away from Petroleum: Green Fuels from Vegetable Oil
• 20-6 Amides: The Least Reactive Carboxylic Acid Derivatives
• Real Life: Medicine 20-2 Killing the Bugs that Kill the Drugs: Antibiotic Wars
• 20-7 Amidates and Their Halogenation: The Hofmann Rearrangement
• 20-8 Alkanenitriles: A Special Class of Carboxylic Acid Derivatives
• 20-9 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 21 Amines and Their Derivatives
• Functional Groups Containing Nitrogen
• 21-1 Naming the Amines
• Real Life: Medicine 21-1 Physiologically Active Amines and Weight Control
• 21-2 Structural and Physical Properties of Amines
• 21-3 Spectroscopy of the Amine Group
• 21-4 Acidity and Basicity of Amines
• 21-5 Synthesis of Amines by Alkylation
• 21-6 Synthesis of Amines by Reductive Amination
• 21-7 Synthesis of Amines from Carboxylic Amides
• 21-8 Reactions of Quaternary Ammonium Salts: Hofmann Elimination
• 21-9 Mannich Reaction: Alkylation of Enols by Iminium Ions
• 21-10 Nitrosation of Amines
• Real Life: Medicine 21-2 Sodium Nitrite as a Food Additive, N-Nitrosodialkanamines, and Cancer
• Real Life: Materials 21-3 Amines in Industry: Nylon, the “Miracle Fiber”
• 21-11 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 22 Chemistry of Benzene Substituents
• Alkylbenzenes, Phenols, and Anilines
• 22-1 Reactivity at the Phenylmethyl (Benzyl) Carbon: Benzylic Resonance Stabilization
• 22-2 Oxidations and Reductions of Substituted Benzenes
• 22-3 Names and Properties of Phenols
• Real Life: Medicine 22-1 Two Phenols in the News: Bisphenol A and Resveratrol
• 22-4 Preparation of Phenols: Nucleophilic Aromatic Substitution
• 22-5 Alcohol Chemistry of Phenols
• Real Life: Medicine 22-2 Aspirin: The Miracle Drug
• 22-6 Electrophilic Substitution of Phenols
• 22-7 An Electrocyclic Reaction of the Benzene Ring: The Claisen Rearrangement
• 22-8 Oxidation of Phenols: Benzoquinones
• Real Life: Biology 22-3 Chemical Warfare in Nature: The Bombardier Beetle
• 22-9 Oxidation-Reduction Processes in Nature
• 22-10 Arenediazonium Salts
• 22-11 Electrophilic Substitution with Arenediazonium Salts: Diazo Coupling
• 22-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 23 Ester Enolates and the Claisen Condensation
• Synthesis of ß-Dicarbonyl Compounds; Acyl Anion Equivalents
• 23-1 ß-Dicarbonyl Compounds: Claisen Condensations
• Real Life: Nature 23-1 Claisen Condensations Assemble Biological Molecules
• 23-2 ß-Dicarbonyl Compounds as Synthetic Intermediates
• 23-3 ß-Dicarbonyl Anion Chemistry: Michael Additions
• 23-4 Acyl Anion Equivalents: Preparation of [H9251]-Hydroxyketones
• Real Life: Nature 23-2 Thiamine: A Natural, Metabolically Active Thiazolium Salt
• 23-5 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 24 Carbohydrates
• Polyfunctional Compounds in Nature
• 24-1 Names and Structures of Carbohydrates
• 24-2 Conformations and Cyclic Forms of Sugars
• 24-3 Anomers of Simple Sugars: Mutarotation of Glucose
• 24-4 Polyfunctional Chemistry of Sugars: Oxidation to Carboxylic Acids
• 24-5 Oxidative Cleavage of Sugars
• 24-6 Reduction of Monosaccharides to Alditols
• 24-7 Carbonyl Condensations with Amine Derivatives
• 24-8 Ester and Ether Formation: Glycosides
• 24-9 Step-by-Step Buildup and Degradation of Sugars
• Real Life: Nature 24-1 Biological Sugar Synthesis
• 24-10 Relative Configurations of the Aldoses: An Exercise in Structure Determination
• 24-11 Complex Sugars in Nature: Disaccharides
• Real Life: Food Chemistry 24-2 Manipulating Our Sweet Tooth
• 24-12 Polysaccharides and Other Sugars in Nature
• Real Life: Medicine 24-3 Sialic Acid, “Bird Flu,” and Rational Drug Design
• 24-13 Worked Example: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 25 Heterocycles
• Heteroatoms in Cyclic Organic Compounds
• 25-1 Naming the Heterocycles
• 25-2 Nonaromatic Heterocycles
• Real Life: Medicine 25-1 Smoking, Nicotine, Cancer, and Medicinal Chemistry
• 25-3 Structures and Properties of Aromatic Heterocyclopentadienes
• 25-4 Reactions of the Aromatic Heterocyclopentadienes
• 25-5 Structure and Preparation of Pyridine: An Azabenzene
• 25-6 Reactions of Pyridine
• Real Life: Biochemistry 25-2 Lessons from Redox-Active Pyridinium Salts in Nature: Nicotinamide Adenine Dinucleotide, Dihydropyridines, and Synthesis
• 25-7 Quinoline and Isoquinoline: The Benzopyridines
• Real Life: Biology 25-3 Folic Acid, Vitamin D, Cholesterol, and the Color of Your Skin
• 25-8 Alkaloids: Physiologically Potent Nitrogen Heterocycles in Nature
• Real Life: Nature 25-4 Nature is Not Always Green: Natural Pesticides
• 25-9 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Chapter 26 Amino Acids, Peptides, Proteins, and Nucleic Acids
• Nitrogen-Containing Polymers in Nature
• 26-1 Structure and Properties of Amino Acids
• Real Life: Medicine 26-1 Arginine and Nitric Oxide in Biochemistry and Medicine
• 26-2 Synthesis of Amino Acids: A Combination of Amine and Carboxylic Acid Chemistry
• 26-3 Synthesis of Enantiomerically Pure Amino Acids
• Real Life: Chemistry 26-2 Enantioselective Synthesis of Optically Pure Amino Acids: Phase-Transfer Catalysis
• 26-4 Peptides and Proteins: Amino Acid Oligomers and Polymers
• 26-5 Determination of Primary Structure: Amino Acid Sequencing
• 26-6 Synthesis of Polypeptides: A Challenge in the Application of Protecting Groups
• 26-7 Merrifield Solid-Phase Peptide Synthesis
• 26-8 Polypeptides in Nature: Oxygen Transport by the Proteins Myoglobin and Hemoglobin
• 26-9 Biosynthesis of Proteins: Nucleic Acids
• Real Life: Medicine 26-3 Synthetic Nucleic Acid Bases and Nucleosides in Medicine
• 26-10 Protein Synthesis Through RNA
• 26-11 DNA Sequencing and Synthesis: Cornerstones of Gene Technology
• Real Life: Forensics 26-4 DNA Fingerprinting
• 26-12 Worked Examples: Integrating the Concepts
• New Reactions
• Important Concepts
• Problems
• Back Matter
• Footnotes
• Answers to Exercises
• Index
• A
• B
• C
• D
• E
• F
• G
• H
• I
• J
• K
• L
• M
• N
• O
• P
• Q
• R
• S
• T
• U
• V
• W
• X
• Y
• Z
• Inside Back Cover
• Back Cover

W tej ofercie kupujesz kod dostępowy umożliwiający dostęp do wskazanej treści. Kod umożliwia dostęp do treści za pomocą przeglądarki WWW, dedykowanej aplikacji iOS (Apple) ze sklepu App Store lub dedykowanej aplikacji Android ze sklepu Play. Kod oraz instrukcje otrzymasz pocztą elektroniczną niezwłocznie po zaksięgowaniu płatności. Brak możliwości pobrania pliku.

Na podstawie art. 38 pkt 13 Ustawy z dnia 30 maja 2014 roku o prawach konsumenta realizując kod dostępowy rezygnujesz z prawa do odstąpienia od umowy zawartej na odległość.

Typ licencji: licencja wieczysta.

BRAK MOŻLIWOŚCI POBRANIA PLIKU.

NIE PRZESYŁAMY PLIKÓW E-MAILEM.